Wednesday, June 30, 2021

Stopping the sulfur shuttle for better batteries

A layer of hierarchically three-dimensional porous graphene greatly suppresses a problem holding back the development of lithium-sulfur batteries.


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As our society and transportation systems become increasingly electrified, scientists worldwide are seeking more efficient and higher capacity storage systems. Researchers at KAUST have made an important contribution by modifying lithium-sulfur (Li-S) batteries to suppress a problem known as polysulfide shuttling.

"The bottleneck in the utilization of renewable energy, especially in transportation, is the need for high-density batteries," says Eman Alhajji, Ph.D. student and first author of the research paper.

Li-S batteries have several potential advantages over the most commonly used types of batteries. They have a higher theoretical energy storage capacity and sulfur is a nontoxic element readily available in nature. Sulfur is also a waste product of the petrochemical industry, so it could be obtained relatively cheaply while increasing the sustainability of another industry.

Polysulfide shuttling involves the movement of sulfur-containing intermediates between the cathode and anode during the battery's chemical processes. This seriously degrades the capacity and recharging ability of the Li-S battery technologies that have been explored to date.

 The KAUST team's solution is based on a layer of graphene. They make this by subjecting a polyimide polymer to laser energy in a process called laser scribing, creating a suitably structured porous material. A key feature is that the material is hierarchically porous in three dimensions, meaning it has an array of pores of different sizes. Nano-sized carbon particles are then added and taken up by the pores to form the final product.

Alhajji and her colleagues found that placing a thin layer of this material between the cathode and anode of a Li-S battery significantly suppresses the polysulfide shuttling.

"Making this freestanding interlayer just a few micrometers thick was a challenge," says Alhajji, adding, "It was fun to roll it like playdough, but then I had to handle it in a very gentle manner, especially during battery assembly."

 Until now, most options proposed to solve the polysulfide shuttling problem have suffered from limitations that make them unsuitable for large-scale commercial application. In contrast, the laser-scribed graphene developed at KAUST is produced by a method that the researchers describe as "scalable and straightforward."

Alhajji won a 2021 Materials Research Society Best Poster Award based on her idea for suppressing the shuttling. "This is a really challenging competition," says Alhajji's supervisor Husam Alshareef, adding, "Only a handful of students from the Materials Science & Engineering program at KAUST have won this award."

KAUST Discovery


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