18 AprPhD DissertationDevice Strategies Directed to Improving the Efficiency of Solution-Processed Solar Cells
Device Strategies Directed to Improving the Efficiency of Solution-Processed Solar Cells
  • Ru-Ze Liang
  • MSE Ph.D. Candidate Supervised by Prof. Pierre Beaujuge
  • Wednesday, April 18, 2018
  • 10:30 AM - 12:30 PM
  • Al-Kindi Building (Bldg. 5), Room 5220
2018-04-18T10:302018-04-18T12:30Asia/RiyadhDevice Strategies Directed to Improving the Efficiency of Solution-Processed Solar CellsMSE PhD Dissertation DefenseAl-Kindi Building (Bldg. 5), Room 5220Mazen E.Mero

​ABSTRACT: In the last decade, organic photovoltaics (OPVs) have been attracting much attention for their low cost, flexibility, low toxicity, solution-processable manufacturing, and feasibility of mass production in large-area modules. Reported power conversion efficiencies (PCE) of organic solar cells have reached more than 10%, even 13% in 2017/18. These promising PCEs can be realized by uncovering important principles: (1) rational molecular design on core/side-chain building blocks, (2) matching of the material energy level, (3) favorable morphology of donor-acceptor (D/A) network, (4) higher carrier mobilities, and (5) suppression of charge recombination within the bulk heterojunction (BHJ). Though these key properties are frequently stated in published studies directed to high-performing organic solar cells, the relationships between these principles remain unclear, which motivates us to fill these gaps.

In the beginning, we show that changing the sequence of donor and acceptor units of the benzodithiophene-core (BDT) SM donors critically impactsmolecular packingand charge transport in BHJ solar cells. Moreover, we find out that by adding small amount of the external solvent additive, the domain size of the SMFQ1 become relatively smaller, resulting in the FF enhancement of ~70% and thus pushing PCE to >6.5%. To further improve the device performance, we utilize another technique of device optimization: Solvent Vapor Annealing (SVA). Compared with solvent additive, the SVA creates a solvent-saturated environment for SMs to re-arrange and crystalize, leading to PCE of >8%, with nearly-free bimolecular recombination. When the systems are shifted from fullerene acceptors to nonfullerene acceptors, using solvent additives in indacenodithiophene-core (IDT) systems significantly reduces the domain size from >500nm to <50nm and also allows the SM donors to orderly packed, rising the PCE from <1% to 4.5%. Furthermore in a similar IDT-based system, it shows unexpectedly high VOC of 1.12 V and low energy loss of 0.5 eV, and high PCE > 6% can be reached by employing the dimethyl disulfide (DMDS) as the SVA solvent to re-organize the morphology from excessive mixing to ordered phase-separated D/A netwrok, together with the exploration of how SVA impact the “All-Small-Molecule” systems. Lastly, taking advantage of the distinct and complementary absorption of fullerene and nonfullerene acceptors, we show that the SM ternary system successfully realizes the high PCE of 11%, good air stability, and scalable property.


  • Mazen E.Mero